Let me attempt to explain the necessary configuration a little bit better, based on an environment I have set up.
STORAGE iSCSI IP ADDRESES:
C1/Ch3: 192.19.21.111
C1/Ch4: 192.19.22.111
C2/Ch3: 192.19.21.112
C2/Ch4: 192.19.22.112
HOST:
vSwitch: iSCSI
VMkernel Adapters:
vmk7: 192.19.21.1
vmk8: 192.19.22.1
iSCSI Software Initiator Sessions:
192.19.21.1 -> 192.19.21.111 (vmk7 to C1/Ch3)
192.19.21.1 -> 192.19.21.112 (vmk7 to C2/Ch3)
192.19.22.1 -> 192.19.22.111 (vmk8 to C1/Ch4)
192.19.22.1 -> 192.19.22.112 (vmk8 to C2/Ch4)
VIRTUAL MACHINE
NIC2: Single NIC attached to iSCSI vSwitch, but provided two IP addresses: 192.19.21.205 and 192.19.22.205
iSCSI Software Initiator Sessions:
192.19.21.205 -> 192.19.21.111 (To C1/Ch3)
192.19.21.205 -> 192.19.21.112 (To C2/Ch3)
192.19.22.205 -> 192.19.22.111 (To C1/Ch4)
192.19.22.205 -> 192.19.22.112 (To C2/Ch4)
Because there are 4 paths to the storage array initiated from the VM, regardless of how many vNICs have been defined, you will see multiple "unvirtualized" disk devices for the same volume presented from the storage array. Installation of E-Series DSM will "virtualize" those paths into a single disk.
Hopefully this is a better explanation than my first reply.