Most likely there are ACLs on those files so the 000 permissions aren't real. You've got a couple of options here.
If you want UNIX style security, then you'll want to chmod the files to what you want (even -R or * should do the trick).
If you want NTFS permissions, then make sure your user mapping are good such that you can access the data. Your NFS user will be mapped to a Windows user and the permissions enforced that way. In this mode, you can basically ignore the UNIX permissions because they aren't used anyway.
The best choice is the side that you want to be able to *change* permissions. Pick the side where you want that to happen and then choose the security style accordingly.
Keep in mind that by default /vol/vol0/etc is usually not a qtree (it should be, IMHO), so you may end up having to change the permission on the root qtree /vol/vol0/ <- note the trailing /. Unless you've converted it to a qtree.