I'm not aware of anything on the filer itself that would give that kind of mapping such as:
vfiler1 - vol1
vfiler1 - vol2
vfiler2 - vol3
vfiler3 - vol4
etc.
It would be fairly easy to carve up the 'vfiler status -r' command to give you that kind of output, if you are familiar with any scripting languages.
Otherwise, do you have DFM/OCUM in your environment? If so the 'dfm volume list' command would give you something close to what you are looking for with volume name and vfiler name on the same line.